All mechanisms

Acid-catalysed addition (hydration)

Year 1
AQA 3.3.5

Alcohol & acid-catalysed chemistry · steam, concentrated H3PO4 catalyst · high temperature and pressure

Reagents: steam, concentrated H3PO4 catalyst · Conditions: high temperature and pressure

Step 1 of 3

CCHHHHH+
  1. 1.The π electrons attack H⁺ from the acid catalyst.

An ethyl carbocation forms.

Step 2 of 3

CH3C+HHOHH
  1. 1.A lone pair on WATER attacks the carbocation. Not OH⁻ — there is no hydroxide in acid.

A protonated alcohol (with O⁺) forms.

Step 3 of 3

CH3CHHO+HH
  1. 1.An O–H bond breaks with both electrons returning to oxygen — H⁺ leaves and the catalyst is regenerated.

Ethanol forms and H⁺ returns to the catalyst pool.

Product: ethanol

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