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Acid-catalysed addition (hydration)
Year 1
AQA 3.3.5
Alcohol & acid-catalysed chemistry · steam, concentrated H3PO4 catalyst · high temperature and pressure
Reagents: steam, concentrated H3PO4 catalyst · Conditions: high temperature and pressure
Step 1 of 3
- 1.The π electrons attack H⁺ from the acid catalyst.
An ethyl carbocation forms.
Step 2 of 3
- 1.A lone pair on WATER attacks the carbocation. Not OH⁻ — there is no hydroxide in acid.
A protonated alcohol (with O⁺) forms.
Step 3 of 3
- 1.An O–H bond breaks with both electrons returning to oxygen — H⁺ leaves and the catalyst is regenerated.
Ethanol forms and H⁺ returns to the catalyst pool.
Product: ethanol
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