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Acid-catalysed elimination (dehydration)
Year 1
AQA 3.3.5
Alcohol & acid-catalysed chemistry · concentrated H2SO4 or H3PO4 · heat
Reagents: concentrated H2SO4 or H3PO4 · Conditions: heat
Step 1 of 3
- 1.A lone pair on the alcohol's oxygen bonds to H⁺ (supplied by the concentrated acid).
The protonated alcohol (oxonium ion) forms.
Step 2 of 3
- 1.The C–O bond breaks heterolytically: both electrons go to the positive oxygen and a molecule of water leaves.
Water leaves, leaving a secondary carbocation.
Step 3 of 3
- 1.A C–H bond on the carbon NEXT to C⁺ collapses in to form the π bond — releasing H⁺, which regenerates the catalyst.
Propene forms and H⁺ is regenerated — dehydration complete.
Product: propene
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