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All calculations

Cell EMF from electrode potentials

Electrode potentials
AQA 7405
ORIGINAL

Ecell = E(reduction at positive electrode) - E(reduction at negative electrode)

Keep both values as reduction potentials: more positive minus more negative.

Board and spec code confirmed against AQA 7405 · registry checked 2026-07-11How this checking works

Work it, then mark it

Do each calculation on paper first, then reveal the mark scheme and tick the marks you actually earned — the same way you should mark past papers.

Q1

E(Cu2+/Cu) = +0.34 V and E(Zn2+/Zn) = -0.76 V. Calculate the standard EMF and state the spontaneous reaction direction.

[3 marks]

Total for this question: 3

Do the calculation on paper first — then mark it.

Where the marks get lost

  • Adding a negative potential without brackets.
  • Reversing a half-equation and also changing the tabulated E value's sign.

Exam tip: Tabulated values stay as reduction potentials; subtract the less positive value from the more positive value.

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