Temperature changes in reactions
GCSE Chemistry (8462) · Required practical 4 — method, variables, the marks examiners report students losing.
Investigate the temperature change of reacting solutions — for example how the volume of one reactant affects the temperature change in neutralisation.
Apparatus
- Polystyrene cup with a lid, standing in a beaker for insulation
- Thermometer (0.5 C resolution) or temperature probe
- Measuring cylinders
- Reactants (e.g. dilute hydrochloric acid and sodium hydroxide)
Method
- 1Measure a fixed volume of the first solution (e.g. 25 cm3 of acid) into the insulated polystyrene cup.
- 2Record its starting temperature.
- 3Add a measured volume of the second reactant and put the lid on.
- 4Stir, and record the highest (exothermic) or lowest (endothermic) temperature reached.
- 5Calculate the temperature change.
- 6Repeat with different volumes of the second reactant (the independent variable).
Variables
Independent
Volume of the second reactant added
Dependent
Maximum (or minimum) temperature change
Control
- Volume and concentration of the first reactant
- Starting temperature
- Insulation and stirring
Results & processing
- Plot temperature change against the volume of reactant added.
- For neutralisation the temperature change peaks when the acid and alkali exactly react — that peak identifies the reacting proportions.
Where students lose marks
Heat lost to the surroundings.
Fix: Use a lid and insulate the cup (polystyrene in a beaker) so the temperature change isn't underestimated.
Recording the temperature at a fixed time instead of at the peak.
Fix: Record the maximum (exothermic) or minimum (endothermic) temperature reached, not the reading after a set time.
Not stirring before reading.
Fix: Stir to spread the heat evenly so the thermometer reads the true temperature.
Improve the method
- A lid and insulation reduce heat loss; take readings continuously to catch the true maximum or minimum.
- Repeat and mean to reduce the effect of random error.
Try it — exam-style
Give two ways a student could reduce heat loss to the surroundings in this experiment.
Explain why a polystyrene cup gives a more accurate temperature change than a glass beaker.
Questions are written in the style of past AQA papers — never copied from them.
Drill it properly
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