Chemistry

Mole calculations

GCSE & A-level

The one skill that turns up on every chemistry paper. Every equation you need — mass, solutions, gases, yield and atom economy — in one place. Flip on Test yourself to check you can recall each one under pressure.

Reading mode — know which equation each quantity needs.

To find…UseUnits / notes
Moles, from a massGCSEn = m ÷ Mm in g; M = Mr in g mol−1
Mass, from molesGCSEm = n × Mrearrangement of the above
Moles, in a solutionGCSEn = c × VV in dm3; c in mol dm−3
ConcentrationGCSEc = n ÷ Vmol dm−3 (× M to get g dm−3)
Moles of a gas (at RTP)GCSEn = V ÷ 24V in dm3 at RTP (÷ 24000 if V in cm3)
Number of particlesGCSEN = n × LL = 6.02×1023 mol−1 (Avogadro)
Moles of a gas (any conditions)A-leveln = pV ÷ RTpV = nRT; p/Pa, V/m3, T/K, R = 8.31
Percentage yieldGCSE(actual ÷ theoretical) × 100compare moles (or mass) of product
Atom economyGCSE(Mr of desired product ÷ ΣMr of reactants) × 100how much of the reactant mass ends up wanted
% by mass of an elementGCSE(n × Ar ÷ Mr) × 100n = number of that atom in the formula

Unit conversions worth memorising

  • 1 dm3 = 1000 cm3 — divide cm3 by 1000 to get dm3.
  • For the ideal-gas equation: 1 m3 = 1000 dm3, and °C + 273 = K.
  • 1 tonne = 1×10⁶ g; 1 kg = 1000 g.

The method examiners reward

  1. Work out moles of what you're given.
  2. Use the balanced equation's ratio to get moles of the target.
  3. Convert those moles to the quantity asked for.

Now put them to work

Reading the equations isn't the same as landing the marks — drill them until the method is automatic.

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