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Chemistry

Key definitions

AQA 8462 · 8462 mark-scheme terms

The definitions AQA marks to the word across all ten 8462 topic areas — from atomic structure and calculations to organic chemistry, analysis, the atmosphere and resource use.

Reading mode — read across, know each one cold.

TermMark-scheme definition
Element
A substance made of only one type of atom.
Compound
A substance made of two or more elements chemically combined (in fixed proportions).
Mixture
Two or more substances (elements or compounds) not chemically combined together.
Pure substance (chemistry)
A single element or compound, not mixed with any other substance.A pure substance melts and boils at one specific temperature.
Isotopes
Atoms of the same element with the same number of protons but different numbers of neutrons.
Atomic number
The number of protons in the nucleus of an atom.
Mass number
The total number of protons and neutrons in the nucleus of an atom.
Relative atomic mass (Ar)
The average mass of the atoms of an element, compared to 1/12th the mass of a carbon-12 atom, taking the abundance of each isotope into account.
Relative formula mass (Mr)
The sum of the relative atomic masses of all the atoms shown in the formula.
Ion
A charged particle formed when an atom (or group of atoms) loses or gains electrons.
Ionic bond
The strong electrostatic force of attraction between oppositely charged ions.
Covalent bond
A shared pair of electrons between two atoms.
Metallic bond
The strong electrostatic attraction between positive metal ions and a sea of delocalised electrons.
Giant covalent structure
A huge lattice of atoms held together by strong covalent bonds (e.g. diamond, graphite, silicon dioxide).
Intermolecular forces
Forces of attraction between molecules; they are weaker than the covalent bonds within molecules.
Mole
The amount of a substance that contains 6.02 x 1023 particles (the Avogadro constant).
Concentration
The amount of solute dissolved in a given volume of solution, in g/dm3 or mol/dm3.
Limiting reactant
The reactant that is completely used up and therefore limits the amount of product formed.
Empirical formula
The simplest whole-number ratio of atoms of each element in a compound.
Percentage yield
(Mass of product actually made / maximum theoretical mass) x 100.
Atom economy
(Relative formula mass of the desired product / sum of relative formula masses of all reactants) x 100.
Exothermic reaction
A reaction that transfers energy to the surroundings, so the temperature of the surroundings increases.
Endothermic reaction
A reaction that takes in energy from the surroundings, so the temperature of the surroundings decreases.
Activation energy
The minimum amount of energy that colliding particles must have to react.
Rate of reaction
The change in the amount of a reactant or product per unit time.
Catalyst
A substance that speeds up the rate of a reaction without being used up, by providing a different pathway with a lower activation energy.
Reversible reaction
A reaction in which the products can react to re-form the reactants.
Dynamic equilibrium
When the forward and reverse reactions occur at the same rate in a closed system, so the concentrations of reactants and products stay constant.
Oxidation
The gain of oxygen, or the loss of electrons.OIL RIG: Oxidation Is Loss, Reduction Is Gain (of electrons).
Reduction
The loss of oxygen, or the gain of electrons.
Acid
A substance that produces H+ ions in aqueous solution.
Base
A substance that neutralises an acid (e.g. a metal oxide or hydroxide).
Alkali
A soluble base that produces OH- ions in aqueous solution.
Strong acid
An acid that is completely ionised in aqueous solution (e.g. hydrochloric, sulfuric, nitric).
Weak acid
An acid that is only partially ionised in aqueous solution (e.g. ethanoic, citric, carbonic).
Neutralisation
The reaction of an acid with a base to make a salt and water.
Electrolysis
The breaking down of an ionic substance, molten or in solution, by passing an electric current through it.
Electrolyte
A molten or dissolved ionic substance that conducts electricity because its ions are free to move.
Hydrocarbon
A compound made of hydrogen and carbon atoms only.
Homologous series
A family of compounds with the same functional group and general formula, similar chemical properties and a gradual trend in physical properties.
Functional group
The atom or group of atoms that determines the characteristic chemical reactions of an organic compound.
Saturated compound
An organic compound containing only single carbon–carbon bonds.
Unsaturated compound
An organic compound containing at least one carbon–carbon double bond.
Cracking
The thermal decomposition of long-chain hydrocarbons into smaller, more useful molecules.
Monomer
A small molecule that can join with many others to form a polymer.
Polymer
A large molecule made from many small molecules (monomers) joined together.
Formulation
A mixture designed as a useful product, with components in carefully measured quantities.
Chromatography
A separation technique in which substances distribute differently between a stationary phase and a mobile phase.
Rf value
The distance travelled by a substance divided by the distance travelled by the solvent.
Greenhouse gas
A gas that absorbs infrared radiation emitted by the Earth's surface and re-emits it in all directions.
Carbon footprint
The total amount of carbon dioxide and other greenhouse gases emitted over the full life cycle of a product, service or event.
Finite resource
A resource that is used faster than it is replaced and will eventually run out.
Renewable resource
A resource that is replenished as it is used.
Potable water
Water that is safe to drink; it is not necessarily pure water.
Life cycle assessment
An assessment of a product's environmental impacts from obtaining raw materials through manufacture and use to disposal.
Corrosion
The destruction of materials by chemical reactions with substances in the environment.
Alloy
A mixture of two or more elements, at least one of which is a metal.
Composite
A material made by combining two or more materials with different properties.

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