All calculations

Rate equation and rate constant

Rate equations
AQA 7405
ORIGINAL

rate = k[A]m[B]n

Orders come from rate data, not balancing coefficients, and k units follow from the final rate equation.

Verified against AQA 7405 (2026 spec)

Work it, then mark it

Do each calculation on paper first, then reveal the mark scheme and tick the marks you actually earned — the same way you should mark past papers.

Q1
4 marks

Doubling [A] while [B] is constant makes rate four times larger. Doubling [B] while [A] is constant has no effect. When [A] = 0.200 mol/dm3, rate = 0.0360 mol/dm3/s. Deduce the rate equation and calculate k with units.

Do the calculation on paper first — then mark it.

Where the marks get lost

  • Reading reaction orders from the balanced equation.
  • Quoting k without deriving its units from rate divided by concentration powers.

Exam tip: Compare pairs where only one concentration changes, then substitute into the completed rate equation.

Calculations are the most trainable marks in chemistry

They come up every paper and reward a clean method. Send me one you keep dropping marks on — your first lesson is free.

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